Solid State
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic
solids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and three
dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids,
number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties.
Band theory of metals, conductors, semiconductors and insulators and n and p type semiconductors.
Solutions
Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in
liquids, solid solutions, colligative properties - relative lowering of vapour pressure, Raoult's law,
elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular
masses using colligative properties, abnormal molecular mass, Van't Hoff factor.
Electrochemistry
Redox reactions, conductance in electrolytic solutions, specific and molar conductivity, variations
of conductivity with concentration, Kohlrausch's Law, electrolysis and law of electrolysis (elementary
idea), dry cell -electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells, Relation between Gibbs
energy change and EMF of a cell, fuel cells, corrosion.
Chemical Kinetics
Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration,
temperature, catalyst; order and molecularity of a reaction, rate law and specific rate
constant,integrated rate equations and half life (only for zero and first order reactions), concept of
collision theory (elementary idea, no mathematical treatment). Activation energy, Arrhenious
equation.
Surface Chemistry
Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on solids, catalysis,
homogenous and heterogenous activity and selectivity; enzyme catalysis colloidal state distinction
between true solutions, colloids and suspension; lyophilic, lyophobic multimolecularand
macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement,electrophoresis,
coagulation, emulsion - types of emulsions.
General Principles and Processes of Isolation of Elements
Principles and methods of extraction - concentration, oxidation, reduction - electrolytic method and
refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.
"p"-Block Elements
Group -15 Elements: General introduction, electronic configuration, occurrence, oxidation states,
trends in physical and chemical properties; Nitrogen preparation properties and uses; compounds
of Nitrogen, preparation and properties of Ammonia and Nitric Acid, Oxides of Nitrogen(Structure
only) ; Phosphorus - allotropic forms, compounds of Phosphorus: Preparation and Properties of
Phosphine, Halides and Oxoacids (elementary idea only).
Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence,
trends in physical and chemical properties,dioxygen: Preparation, Properties and uses, classification
of Oxides, Ozone, Sulphur -allotropic forms; compounds of Sulphur: Preparation Properties and
uses of Sulphur-dioxide, Sulphuric Acid: industrial process of manufacture, properties and uses;
Oxoacids of Sulphur (Structures only).
Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence,
trends in physical and chemical properties; compounds of halogens, Preparation, properties and
uses of Chlorine and Hydrochloric acid, interhalogen compounds, Oxoacids of halogens (structures
only).
Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physical
and chemical properties, uses.
"d" and "f" Block Elements
General introduction, electronic configuration, occurrence and characteristics of transition metals,
general trends in properties of the first row transition metals - metallic character, ionization enthalpy,
oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds,
alloy formation, preparation and properties of K2Cr2O7 and KMnO4.
Lanthanoids - Electronic configuration, oxidation states, chemical reactivity and lanthanoid
contraction and its consequences.
Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids.
Coordination Compounds
Coordination compounds - Introduction, ligands, coordination number, colour, magnetic properties
and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner's
theory, VBT, and CFT; structure and stereoisomerism, importance of coordination compounds (in
qualitative inclusion, extraction of metals and biological system).
Haloalkanes and Haloarenes.
Haloalkanes: Nomenclature, nature of C -X bond, physical and chemical properties, mechanism of
substitution reactions, optical rotation.
Haloarenes: Nature of C -X bond, substitution reactions (Directive influence of halogen in
monosubstituted compounds only).
Uses and environmental effects of - dichloromethane, trichloromethane, tetrachloromethane,
iodoform, freons, DDT.
Alcohols, Phenols and Ethers
Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary
alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration,
uses with special reference to methanol and ethanol.
Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of
phenol, electrophillic substitution reactions, uses of phenols.
Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.
Aldehydes, Ketones and Carboxylic Acids
Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical
and chemical properties, mechanism of nucleophilic addition, reactivity of alpha hydrogen in
aldehydes: uses.
Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical
properties; uses.
Organic compounds containing Nitrogen
Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical
properties, uses, identification of primary, secondary and tertiary amines.
Cyanides and Isocyanides - will be mentioned at relevant places in text.
Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.
Biomolecules
Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L
configuration oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose,
glycogen); Importance of carbohydrates.
Proteins -Elementary idea of - amino acids, peptide bond, polypeptides, proteins, structure of
proteins - primary, secondary, tertiary structure and quaternary structures (qualitative idea only),
denaturation of proteins; enzymes. Hormones - Elementary idea excluding structure.
Vitamins - Classification and functions.
Nucleic Acids: DNA and RNA.
Polymers
Classification - natural and synthetic, methods of polymerization (addition and condensation),
copolymerization, some important polymers: natural and synthetic like polythene, nylon polyesters,
bakelite, rubber. Biodegradable and non-biodegradable polymers.
Chemistry in Everyday life
Chemicals in medicines - analgesics, tranquilizers antiseptics, disinfectants, antimicrobials,
antifertility drugs, antibiotics, antacids, antihistamines.
Chemicals in food - preservatives, artificial sweetening agents, elementary idea of antioxidants.
Cleansing agents- soaps and detergents, cleansing action.